Improved catalytic performance of hierarchical ZSM-5 synthesized by desilication with surfactants

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

Hierarchical ZSM-5 zeolites were synthesized by alkaline desilication and a surfactant induced re-assembly. Contrary to the purely alkaline desilicated zeolites a strong increase in external surface area, a narrow pore size distribution of 3-10 nm and a decreased Brönsted acidity could be achieved when using CTAB as a surfactant throughout the alkaline treatment. The hierarchical pore system and the decreased acidity lead to an improved catalyst lifetime in the methanol to hydrocarbon conversion. A further improvement could be accomplished by increasing the surfactant concentration during the desilication re-assembly preparation. Tailoring of mesopore size and specific surface area was achieved using surfactants with different chain lengths.

Details

OriginalspracheEnglisch
Seiten (von - bis)148-157
Seitenumfang10
FachzeitschriftMicroporous and mesoporous materials
Jahrgang165
PublikationsstatusVeröffentlicht - 1 Jan. 2013
Peer-Review-StatusJa

Schlagworte

Schlagwörter

  • Hierarchical ZSM-5, Improved catalytic lifetime, Mesoporous ZSM-5, Methanol to hydrocarbon, Surfactant assisted desilication

Bibliotheksschlagworte