“Impact of hydride composite materials on thermochemical hydrogen compression”

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Marius Lau - , Fraunhofer Institute for Manufacturing Technology and Advanced Materials (Author)
  • Oliver Ehrensberger - , Fraunhofer Institute for Manufacturing Technology and Advanced Materials, TUD Dresden University of Technology, MUT Advanced Heating GmbH (Author)
  • Thomas Weißgärber - , Chair of Powder Metallurgy, Fraunhofer Institute for Manufacturing Technology and Advanced Materials, TUD Dresden University of Technology (Author)
  • Felix Heubner - , Fraunhofer Institute for Manufacturing Technology and Advanced Materials (Author)

Abstract

The formation of a hydride from a metal or intermetallic alloy is an exothermic reversible chemical reaction. The thermodynamic properties governing hydride formation facilitate their thermochemical applications, such as hydrogen compression. Thermal transport inside the materials is of highest importance for system dynamics and its productivity. In this contribution, we demonstrate a two-stage thermochemical hydrogen compressor using the AB5 alloy LaNi5 in the first stage and an AB2 alloy TiMn2 (Hydralloy®) in the second stage. To evaluate the impact of the thermal conductivity of the materials, the productivity of the compressor was compared for pure metal hydride compacts (MH) and metal hydride composite materials (MHC). Compared to pure MH pellets, the MHC used in this study contain expanded natural graphite (ENG), a secondary phase with highest thermal conductivity. As the radial thermal conductivity of the MHC increased, the time required for the loading, temperature change and unloading steps was successfully reduced by 400%. Productivity was increased by over 320 % from 14 NlH2/(kgMaterial*h) to 44 NlH2/(kgMaterial*h). Overall, MHC have the potential to simplify handling, reactor design and reduce investment costs for thermochemical compression systems. Thus, MHC have highest impact and potential for thermochemical applications.

Details

Original languageEnglish
Pages (from-to)562-570
Number of pages9
JournalInternational journal of hydrogen energy
Volume71
Publication statusPublished - 19 Jun 2024
Peer-reviewedYes

Keywords

Sustainable Development Goals

Keywords

  • Hydralloy, LaNi, Metal hydride composite, Thermochemical hydrogen compression, TiMn