High-pressure synthesis and exotic heavy-fermion behaviour of the filled skutterudite SmPt4Ge12

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • R. Gumeniuk - , Max Planck Institute for Chemical Physics of Solids (Author)
  • M. Schöneich - , TUD Dresden University of Technology (Author)
  • A. Leithe-Jasper - , Max Planck Institute for Chemical Physics of Solids (Author)
  • W. Schnelle - , Max Planck Institute for Chemical Physics of Solids (Author)
  • M. Nicklas - , Max Planck Institute for Chemical Physics of Solids (Author)
  • H. Rosner - , Max Planck Institute for Chemical Physics of Solids (Author)
  • A. Ormeci - , Max Planck Institute for Chemical Physics of Solids (Author)
  • U. Burkhardt - , Max Planck Institute for Chemical Physics of Solids (Author)
  • M. Schmidt - , Max Planck Institute for Chemical Physics of Solids (Author)
  • U. Schwarz - , Max Planck Institute for Chemical Physics of Solids (Author)
  • M. Ruck - , Chair of Inorganic Chemistry II, TUD Dresden University of Technology (Author)
  • Yu Grin - , Max Planck Institute for Chemical Physics of Solids (Author)

Abstract

Ternary samarium-filled platinum-germanium skutterudite SmPt 4Ge12 was prepared at a pressure of 5.0(0.5) GPa and a temperature of 1070(70) K. The compound crystallizes in the cubic space group Im3̄ (a = 8.6069(4) Å) and is isotypic with LaFe4P 12. X-ray absorption spectroscopy measurements show that samarium in SmPt4Ge12 has a temperature-independent intermediate valence (v = 2.90±0.03). Magnetization data reveal Van Vleck paramagnetism above ∼50 K. The low-temperature specific heat displays a broad anomaly centred at 2.9K and a large linear coefficient γ′ = 450 mJ mol-1 K-2 suggesting heavy-fermion behaviour. Low-temperature electrical resistivity shows a temperature dependence reminiscent of the Kondo effect. Density functional calculations result in an electronic structure that is, apart from the Sm 4 f contributions, very similar to LaPt4Ge12.

Details

Original languageEnglish
Article number103035
JournalNew journal of physics
Volume12
Publication statusPublished - 19 Oct 2010
Peer-reviewedYes

External IDs

ORCID /0000-0002-2391-6025/work/159171933

Keywords

ASJC Scopus subject areas