Harnessing Phase Transitions in Antiferroelectric ZrO2 Using the Size Effect

Research output: Contribution to journalResearch articleContributedpeer-review


  • Patrick D. Lomenzo - , TUD Dresden University of Technology (Author)
  • Monica Materano - , Chair of Nanoelectronics, TUD Dresden University of Technology (Author)
  • Terence Mittmann - , TUD Dresden University of Technology (Author)
  • Pratyush Buragohain - , University of Nebraska-Lincoln (Author)
  • Alexei Gruverman - , University of Nebraska-Lincoln (Author)
  • Takanori Kiguchi - , Tohoku University (Author)
  • Thomas Mikolajick - , Chair of Nanoelectronics, TUD Dresden University of Technology (Author)
  • Uwe Schroeder - , TUD Dresden University of Technology (Author)


The unique nonlinear dielectric properties of antiferroelectric (AFE) oxides are promising for advancements in solid state supercapacitor, actuator, and memory technologies. AFE behavior in high-k ZrO2 is of particular technological interest, but the origin of antiferroelectricity in ZrO2 remains questionable. The theory of reversible electric field-induced phase transitions between the nonpolar P42/nmc tetragonal phase and the polar Pca21 orthorhombic phase is experimentally tested with local structural and electromechanical characterization of AFE ZrO2 thin films. Piezoresponse force microscopy identifies signature evidence of a field-induced phase transition. A significant size effect in AFE ZrO2 is experimentally observed as film thickness is scaled down from 14.7 to 4.3 nm. The size effect is explained by modifications to the phase transition energy barrier heights ranging from 0.6 to 7.6 meV f.u−1 depending on crystallite size and in-plane compressive strain with decreasing ZrO2 film thickness. Using the size effect, it is possible to double the energy storage density in ZrO2 from 20 J cm−3 to greater than 40 J cm−3, thus highlighting a feasible route for superior performance in AFE fluorite supercapacitors.


Original languageEnglish
Article number2100556
JournalAdvanced electronic materials
Issue number1
Publication statusPublished - 7 Oct 2021

External IDs

unpaywall 10.1002/aelm.202100556
Mendeley a0e694c1-6a34-3071-89f6-3af9430b2bb5
ORCID /0000-0003-3814-0378/work/142256164