Formation of [Ph2P5](+), [Ph4P6](2+), and [Ph6P7](3+) Cationic Clusters by Consecutive Insertions of [Ph2P](+) into P-P Bonds of the Tetrahedron
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Positively phosphorus: A solvent-free melt system (P4/Ph2PCl/GaCl3) represents a powerful medium for the functionalization of the P4 tetrahedron to form new cationic phosphorus-rich organophosphorus cage and cluster systems, such as [Ph2P5]+, [Ph4P6]2+, and [Ph6P7]3+ (see picture), by insertion of [Ph2P]+ into PP bonds.
Details
| Original language | English |
|---|---|
| Journal | Angewandte Chemie International Edition |
| Volume | 48 |
| Issue number | 2 |
| Publication status | Published - 2009 |
| Peer-reviewed | Yes |
External IDs
| WOS | 000262458300005 |
|---|---|
| Scopus | 58249104061 |