Formation of [Ph2P5](+), [Ph4P6](2+), and [Ph6P7](3+) Cationic Clusters by Consecutive Insertions of [Ph2P](+) into P-P Bonds of the Tetrahedron

Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung

Beitragende

Abstract

Positively phosphorus: A solvent-free melt system (P4/Ph2PCl/GaCl3) represents a powerful medium for the functionalization of the P4 tetrahedron to form new cationic phosphorus-rich organophosphorus cage and cluster systems, such as [Ph2P5]+, [Ph4P6]2+, and [Ph6P7]3+ (see picture), by insertion of [Ph2P]+ into PP bonds.

Details

OriginalspracheEnglisch
FachzeitschriftAngewandte Chemie International Edition
Jahrgang48
Ausgabenummer2
PublikationsstatusVeröffentlicht - 2009
Peer-Review-StatusJa

Externe IDs

WOS 000262458300005
Scopus 58249104061

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Bibliotheksschlagworte