Formation and Characterization of Transparent Conductive Oxide SnO2:Ta Grown at Low Deposition Temperature

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Contributors

  • Cecilia Bauden - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Justus Haag - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Alvaro Mendez - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Nano4Energy SL (Author)
  • Frans Munnik - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Fabian Ganss - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Ambiörn Wennberg - , Nano4Energy SL (Author)
  • Ivan Fernandez - , Nano4Energy SL (Author)
  • Ivan Kaban - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Harish Parala - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Anjana Devi - , Chair of Materials Chemistry (gB/IFW), Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Matthias Krause - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)

Abstract

The formation of the transparent conductive oxide SnO2:Ta by reactive direct-current magnetron sputtering at a low temperature of 225°C was studied as a function of the oxygen flow rate using a pilot-scale setup. Beginning with a mixture of β-Sn and SnO as majority phases and minority fractions of Sn3O4 and SnO2 at very low O2 flows, up to the formation of phase-pure rutile-type SnO2:Ta at higher flow rates, a systematic evolution of the phase structure is observed. The SnO2:Ta (0.70 at.% Ta) film grown at optimized flow conditions exhibits a transmittance of >80% from 500 to 2500 nm and a specific resistivity of 0.3 Ω cm. While the transmittance is competitive, the resistivity is in the upper range of that reported for low-temperature-deposited SnO2:Ta films in research lab studies. Based on X-ray diffraction, Raman spectroscopy, optical spectroscopy, and X-ray photoelectron spectroscopy, we conclude that the small crystallite size, microstrain, and point defects caused by the low growth temperature might prevent charge carrier activation, even though the Ta dopant is incorporated as Ta5+ in the rutile-type SnO2 lattice.

Details

Original languageEnglish
Article numbere202500625
JournalPhysica Status Solidi (B): Basic Research
Volume263
Issue number3
Publication statusPublished - Mar 2026
Peer-reviewedYes

Keywords

Keywords

  • low-temperature processing, magnetron sputtering, Ta-doped tin oxide, TCOs, transparent conductive oxides