Foam-derived multiferroic BiFeO3 nanoparticles and integration into transparent polymer nanocomposites
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Transparent BiFeO3/PMMA (PMMA = poly(methyl methacrylate)) nanocomposites with a thickness up to 40 μm are obtained via solution film casting of BiFeO3 nanoparticle dispersions. The multiferroic BiFeO3 nanoparticles are obtained in a space confined crystallisation process in a porous carbon matrix and subsequent removal of the matrix. The average crystallite size ranges from 46 nm to 106 nm for materials synthesised at 803 K and 903 K respectively, but, at higher temperature, significant amounts of side products are detected by means of X-ray powder diffraction. The nanoparticles are multiferroic with a magnetic coercivity of 1.88 A m-1 at 400 K and a polarisation of up to 1.04 μC/cm2 at 65 kV/cm (298 K). Surface functionalisation using oleic acid allows the integration into PMMA films with a high transmittance.
Details
Original language | English |
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Pages (from-to) | 1-15 |
Number of pages | 15 |
Journal | Journal of experimental nanoscience |
Volume | 3 |
Issue number | 1 |
Publication status | Published - 16 May 2008 |
Peer-reviewed | Yes |
Keywords
ASJC Scopus subject areas
Keywords
- BiFeO, Multiferroic, Nanocomposite, Nanoparticles