Electron-induced structural changes in flax fiber reinforced PLA/PCL composites, analyzed using the rule of mixtures

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Piotr Rytlewski - , Kazimierz Wielki University (Author)
  • Uwe Gohs - , Institute of Lightweight Engineering and Polymer Technology, Dresden University of Applied Sciences (HTW) (Author)
  • Magdalena Stepczyńska - , Kazimierz Wielki University (Author)
  • Rafal Malinowski - , Institute for Engineering of Polymer Materials and Dyes (Author)
  • Tomasz Karasiewicz - , Kazimierz Wielki University (Author)
  • Krzysztof Moraczewski - , Kazimierz Wielki University (Author)

Abstract

The paper presents the effect of electron treatment on the various properties of flax fibers (20 wt%; 5 mm in length) reinforced PLA/PCL (70:30) composites. To enhance the intensity of the electron-induced cross-linking reactions, triallyl isocyanurate (TAIC) as a cross-linking agent was also added (up to 3 wt%). The composites were manufactured by conventional extrusion, granulation, and injection molding techniques, and then electron irradiated at doses of up to 60 kGy. The structural changes were determined using mechanical testing (tensile strength, impact strength, dynamic mechanical analysis), gel content analysis, thermogravimetry, and differential scanning calorimetry (DSC). The modified composites were also subjected to enzymatic biodegradation and industrial composting. An important novelty aspect of the presented research, additionally to the new material composition, is the use of the rule of mixtures in the assessment of the effect of electron treatment on the interfacial interactions of dispersed PCL in the continuous phase of PLA, in the presence of flax fibers. PCL was dispersed in the PLA phase with an average phase size of a few micrometers. Based on the rule of mixtures, it was found that without TAIC, the predominantly degraded PLA phase-initiated cross-linking of the dispersed PCL phase, contributing to the interphase adhesion enhancement reflected in improved mechanical properties. To apply this model, it was required to refer to the previously published results of analogous composites with homopolymer matrix (PLA or PCL).

Details

Original languageEnglish
Article number115587
Number of pages10
Journal Industrial crops and products : an international journal
Volume188, Part A
Early online date18 Sept 2022
Publication statusPublished - 15 Nov 2022
Peer-reviewedYes

External IDs

Mendeley 31729440-6bd0-3db4-8504-e43464b5b8a2

Keywords

ASJC Scopus subject areas

Keywords

  • Biodegradation, Electron treatment, Flax fibers, Polymer composites, Rule of mixtures