Dynamical theory for the battery's electromotive force
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
We propose a dynamical theory of how the chemical energy stored in a battery generates the electromotive force (emf). In this picture, the battery's half-cell acts as an engine, cyclically extracting work from its underlying chemical disequilibrium. We show that the double layer at the electrode-electrolyte interface can exhibit a rapid self-oscillation that pumps an electric current, thus accounting for the persistent conversion of chemical energy into electrical work equal to the emf times the separated charge. We suggest a connection between this mechanism and the slow self-oscillations observed in various electrochemical cells, including batteries, as well as the enhancement of the current observed when ultrasound is applied to the half-cell. Finally, we propose more direct experimental tests of the predictions of this dynamical theory.
Details
| Original language | English |
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| Pages (from-to) | 9428-9439 |
| Number of pages | 12 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 23 |
| Issue number | 15 |
| Publication status | Published - 21 Apr 2021 |
| Peer-reviewed | Yes |
| Externally published | Yes |
External IDs
| PubMed | 33885063 |
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| ORCID | /0000-0002-6269-0540/work/172082500 |