Dynamical theory for the battery's electromotive force

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Robert Alicki - , University of Gdańsk (Author)
  • David Gelbwaser-Klimovsky - , Massachusetts Institute of Technology (MIT) (Author)
  • Alejandro Jenkins - , University of Gdańsk, University of Costa Rica (Author)
  • Elizabeth Von Hauff - , Vrije Universiteit Amsterdam (VU) (Author)

Abstract

We propose a dynamical theory of how the chemical energy stored in a battery generates the electromotive force (emf). In this picture, the battery's half-cell acts as an engine, cyclically extracting work from its underlying chemical disequilibrium. We show that the double layer at the electrode-electrolyte interface can exhibit a rapid self-oscillation that pumps an electric current, thus accounting for the persistent conversion of chemical energy into electrical work equal to the emf times the separated charge. We suggest a connection between this mechanism and the slow self-oscillations observed in various electrochemical cells, including batteries, as well as the enhancement of the current observed when ultrasound is applied to the half-cell. Finally, we propose more direct experimental tests of the predictions of this dynamical theory.

Details

Original languageEnglish
Pages (from-to)9428-9439
Number of pages12
JournalPhysical Chemistry Chemical Physics
Volume23
Issue number15
Publication statusPublished - 21 Apr 2021
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 33885063
ORCID /0000-0002-6269-0540/work/172082500