Dynamical theory for the battery's electromotive force
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
We propose a dynamical theory of how the chemical energy stored in a battery generates the electromotive force (emf). In this picture, the battery's half-cell acts as an engine, cyclically extracting work from its underlying chemical disequilibrium. We show that the double layer at the electrode-electrolyte interface can exhibit a rapid self-oscillation that pumps an electric current, thus accounting for the persistent conversion of chemical energy into electrical work equal to the emf times the separated charge. We suggest a connection between this mechanism and the slow self-oscillations observed in various electrochemical cells, including batteries, as well as the enhancement of the current observed when ultrasound is applied to the half-cell. Finally, we propose more direct experimental tests of the predictions of this dynamical theory.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 9428-9439 |
Seitenumfang | 12 |
Fachzeitschrift | Physical Chemistry Chemical Physics |
Jahrgang | 23 |
Ausgabenummer | 15 |
Publikationsstatus | Veröffentlicht - 21 Apr. 2021 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
PubMed | 33885063 |
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ORCID | /0000-0002-6269-0540/work/172082500 |