Distributed Feedback Lasing in Thermally Imprinted Phase-Stabilized CsPbI3 Thin Films

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Naho Kurahashi - , University of Wuppertal (Author)
  • Manuel Runkel - , University of Wuppertal (Author)
  • Cedric Kreusel - , University of Wuppertal (Author)
  • Maximilian Schiffer - , University of Wuppertal (Author)
  • Timo Maschwitz - , University of Wuppertal (Author)
  • Timo Kraus - , University of Wuppertal (Author)
  • Kai Oliver Brinkmann - , University of Wuppertal (Author)
  • Ralf Heiderhoff - , University of Wuppertal (Author)
  • Maximilian Buchmüller - , University of Wuppertal (Author)
  • Sven Oliver Schumacher - , University of Wuppertal (Author)
  • Julius Brunner - , Chair of Emerging Electronic Technologies (gB/IFW and cfaed), Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Detlef Rogalla - , Ruhr University Bochum (Author)
  • Sercan Özen - , University of Potsdam (Author)
  • Felix Lang - , University of Potsdam (Author)
  • Yana Vaynzof - , Center for Advancing Electronics Dresden (cfaed), Chair of Emerging Electronic Technologies (gB/IFW and cfaed), Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Patrick Görrn - , University of Wuppertal (Author)
  • Thomas Riedl - , University of Wuppertal (Author)

Abstract

All-inorganic cesium lead halide perovskites (CsPbX3, with X = I, Br, Cl) are of great interest for light-emitting diodes and lasers, as they promise improved thermal stability compared to their organic–inorganic analogues. However, among this family of materials, CsPbI3 shows a detrimental phase instability that causes the perovskite to convert to a thermodynamically preferred non-perovskite phase (yellow phase) at room temperature. In fact, reports on lasers using thin films of CsPbI3 as gain medium are missing, as of yet. Here, the first distributed feedback (DFB) lasers based on CsPbI3 thin films are presented with a resonator directly patterned into the perovskite by thermal nanoimprint. This breakthrough is unlocked by the additive polyvinyl pyrrolidone (PVP), that affords the formation of perovskite layers consisting of phase stable γ-CsPbI3 nanocrystals, that are even preserved during thermal imprint at 170 °C. The DFB lasers show a low lasing threshold of 45 µJ cm−2 at room temperature under optical pumping and a tunable emission in the deep red spectral region between 714.1 to 723.4 nm. It is anticipated that the findings of this work will have a broad relevance for future electrically driven perovskite lasers and for light-emitting diodes based on CsPbI3 as active medium.

Details

Original languageEnglish
Article number2405976
JournalAdvanced functional materials
Volume34
Issue number45
Publication statusPublished - 2024
Peer-reviewedYes

External IDs

Mendeley 090a50a2-e7be-3d45-9a13-00a8a7d1ed90

Keywords

Keywords

  • all-inorganic halide perovskites, distributed feedback lasers, nanoimprint, perovskite lasers, thin films