Distributed Feedback Lasing in Thermally Imprinted Phase-Stabilized CsPbI3 Thin Films

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Naho Kurahashi - , Bergische Univertsität Wuppertal (Autor:in)
  • Manuel Runkel - , Bergische Univertsität Wuppertal (Autor:in)
  • Cedric Kreusel - , Bergische Univertsität Wuppertal (Autor:in)
  • Maximilian Schiffer - , Bergische Univertsität Wuppertal (Autor:in)
  • Timo Maschwitz - , Bergische Univertsität Wuppertal (Autor:in)
  • Timo Kraus - , Bergische Univertsität Wuppertal (Autor:in)
  • Kai Oliver Brinkmann - , Bergische Univertsität Wuppertal (Autor:in)
  • Ralf Heiderhoff - , Bergische Univertsität Wuppertal (Autor:in)
  • Maximilian Buchmüller - , Bergische Univertsität Wuppertal (Autor:in)
  • Sven Oliver Schumacher - , Bergische Univertsität Wuppertal (Autor:in)
  • Julius Brunner - , Professur für Neuartige Elektroniktechnologien (gB/IFW und cfaed), Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Detlef Rogalla - , Ruhr-Universität Bochum (Autor:in)
  • Sercan Özen - , Universität Potsdam (Autor:in)
  • Felix Lang - , Universität Potsdam (Autor:in)
  • Yana Vaynzof - , Center for Advancing Electronics Dresden (cfaed), Professur für Neuartige Elektroniktechnologien (gB/IFW und cfaed), Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Patrick Görrn - , Bergische Univertsität Wuppertal (Autor:in)
  • Thomas Riedl - , Bergische Univertsität Wuppertal (Autor:in)

Abstract

All-inorganic cesium lead halide perovskites (CsPbX3, with X = I, Br, Cl) are of great interest for light-emitting diodes and lasers, as they promise improved thermal stability compared to their organic–inorganic analogues. However, among this family of materials, CsPbI3 shows a detrimental phase instability that causes the perovskite to convert to a thermodynamically preferred non-perovskite phase (yellow phase) at room temperature. In fact, reports on lasers using thin films of CsPbI3 as gain medium are missing, as of yet. Here, the first distributed feedback (DFB) lasers based on CsPbI3 thin films are presented with a resonator directly patterned into the perovskite by thermal nanoimprint. This breakthrough is unlocked by the additive polyvinyl pyrrolidone (PVP), that affords the formation of perovskite layers consisting of phase stable γ-CsPbI3 nanocrystals, that are even preserved during thermal imprint at 170 °C. The DFB lasers show a low lasing threshold of 45 µJ cm−2 at room temperature under optical pumping and a tunable emission in the deep red spectral region between 714.1 to 723.4 nm. It is anticipated that the findings of this work will have a broad relevance for future electrically driven perovskite lasers and for light-emitting diodes based on CsPbI3 as active medium.

Details

OriginalspracheEnglisch
Aufsatznummer2405976
FachzeitschriftAdvanced functional materials
Jahrgang34
Ausgabenummer45
PublikationsstatusVeröffentlicht - 2024
Peer-Review-StatusJa

Externe IDs

Mendeley 090a50a2-e7be-3d45-9a13-00a8a7d1ed90

Schlagworte

Schlagwörter

  • all-inorganic halide perovskites, distributed feedback lasers, nanoimprint, perovskite lasers, thin films