Correlation length of hydrophobic polyelectrolyte solutions

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • D. Baigl - , French National Centre for Scientific Research (CNRS) (Author)
  • R. Ober - , French National Centre for Scientific Research (CNRS) (Author)
  • D. Qu - , Max Planck Institute of Colloids and Interfaces, Paris-Sud University (Author)
  • A. Fery - , Max Planck Institute of Colloids and Interfaces (Author)
  • C. E. Williams - , French National Centre for Scientific Research (CNRS) (Author)

Abstract

The combination of two techniques (Small Angle X-ray Scattering and Atomic Force Microscopy) has allowed us to measure in reciprocal and real space the correlation length ξ of salt-free aqueous solutions of a highly charged hydrophobic polyelectrolyte as a function of the polymer concentration Cp, charge fraction f and chain length N. Contrary to the classical behaviour of hydrophilic polyelectrolytes in the strong-coupling limit, ξ is strongly dependent on f. In particular, a continuous transition has been observed from ξ ∼ Cp-1/2 to ξ ∼ Cp-1/3 when f decreased from 100% to 35%. We interpret this unusual behaviour as the consequence of the two features characterising the hydrophobic polyelectrolytes: the pearl necklace conformation of the chains and the anomalously strong reduction of the effective charge fraction.

Details

Original languageEnglish
Pages (from-to)588-594
Number of pages7
JournalEurophysics letters
Volume62
Issue number4
Publication statusPublished - May 2003
Peer-reviewedYes
Externally publishedYes

Keywords