Correlation length of hydrophobic polyelectrolyte solutions
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Contributors
Abstract
The combination of two techniques (Small Angle X-ray Scattering and Atomic Force Microscopy) has allowed us to measure in reciprocal and real space the correlation length ξ of salt-free aqueous solutions of a highly charged hydrophobic polyelectrolyte as a function of the polymer concentration Cp, charge fraction f and chain length N. Contrary to the classical behaviour of hydrophilic polyelectrolytes in the strong-coupling limit, ξ is strongly dependent on f. In particular, a continuous transition has been observed from ξ ∼ Cp-1/2 to ξ ∼ Cp-1/3 when f decreased from 100% to 35%. We interpret this unusual behaviour as the consequence of the two features characterising the hydrophobic polyelectrolytes: the pearl necklace conformation of the chains and the anomalously strong reduction of the effective charge fraction.
Details
Original language | English |
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Pages (from-to) | 588-594 |
Number of pages | 7 |
Journal | Europhysics letters |
Volume | 62 |
Issue number | 4 |
Publication status | Published - May 2003 |
Peer-reviewed | Yes |
Externally published | Yes |