Correlation length of hydrophobic polyelectrolyte solutions

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • D. Baigl - , Centre national de la recherche scientifique (CNRS) (Autor:in)
  • R. Ober - , Centre national de la recherche scientifique (CNRS) (Autor:in)
  • D. Qu - , Max Planck Institute of Colloids and Interfaces, Université Paris-Sud (Autor:in)
  • A. Fery - , Max Planck Institute of Colloids and Interfaces (Autor:in)
  • C. E. Williams - , Centre national de la recherche scientifique (CNRS) (Autor:in)

Abstract

The combination of two techniques (Small Angle X-ray Scattering and Atomic Force Microscopy) has allowed us to measure in reciprocal and real space the correlation length ξ of salt-free aqueous solutions of a highly charged hydrophobic polyelectrolyte as a function of the polymer concentration Cp, charge fraction f and chain length N. Contrary to the classical behaviour of hydrophilic polyelectrolytes in the strong-coupling limit, ξ is strongly dependent on f. In particular, a continuous transition has been observed from ξ ∼ Cp-1/2 to ξ ∼ Cp-1/3 when f decreased from 100% to 35%. We interpret this unusual behaviour as the consequence of the two features characterising the hydrophobic polyelectrolytes: the pearl necklace conformation of the chains and the anomalously strong reduction of the effective charge fraction.

Details

OriginalspracheEnglisch
Seiten (von - bis)588-594
Seitenumfang7
FachzeitschriftEurophysics letters
Jahrgang62
Ausgabenummer4
PublikationsstatusVeröffentlicht - Mai 2003
Peer-Review-StatusJa
Extern publiziertJa

Schlagworte