Competition between 3d and 4f magnetism in Ce2 Fe2 S5

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • A. Schneidewind - , TUD Dresden University of Technology (Author)
  • A. M. Mills - , TUD Dresden University of Technology (Author)
  • W. Schnelle - , Max Planck Institute for Chemical Physics of Solids (Author)
  • O. Stockert - , Max Planck Institute for Chemical Physics of Solids (Author)
  • B. Ouladdiaf - , ILL - Institut Laue-Langevin (Author)
  • M. Ruck - , Chair of Inorganic Chemistry II (Author)

Abstract

Magnetic susceptibility measurements and neutron powder diffraction were performed on the rare-earth transition-metal sulfide Ce2 Fe2 S5 to study the effect of the substitution of nonmagnetic La3 +(4 f0) by Ce3 +4 f1) . Ce2 Fe2 S5, which is isostructural to La2 Fe2 S5, contains Fe2 + ions within chains of iron-sulfur octahedra and tetrahedra that are interconnected by Ce2 + ions. Two antiferromagnetic phases, both with the propagation vector τ = (frac(1, 2) frac(1, 2) 0), are observed: at 5 K ≤ T ≤ 80 K ordering of the Fe2 + moments is found; at T ≤ 5 K the Ce3 + ions also participate in the magnetic ordering.

Details

Original languageEnglish
Pages (from-to)1706-1708
Number of pages3
JournalJournal of magnetism and magnetic materials
Volume310
Issue number2 Suppl Part 2
Publication statusPublished - Mar 2007
Peer-reviewedYes

External IDs

ORCID /0000-0002-2391-6025/work/166325845

Keywords

Keywords

  • Cerium, Iron, Magnetic structure, Neutron scattering, Rare earth compounds