Competition between 3d and 4f magnetism in Ce2 Fe2 S5
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Magnetic susceptibility measurements and neutron powder diffraction were performed on the rare-earth transition-metal sulfide Ce2 Fe2 S5 to study the effect of the substitution of nonmagnetic La3 +(4 f0) by Ce3 +4 f1) . Ce2 Fe2 S5, which is isostructural to La2 Fe2 S5, contains Fe2 + ions within chains of iron-sulfur octahedra and tetrahedra that are interconnected by Ce2 + ions. Two antiferromagnetic phases, both with the propagation vector τ = (frac(1, 2) frac(1, 2) 0), are observed: at 5 K ≤ T ≤ 80 K ordering of the Fe2 + moments is found; at T ≤ 5 K the Ce3 + ions also participate in the magnetic ordering.
Details
| Original language | English |
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| Pages (from-to) | 1706-1708 |
| Number of pages | 3 |
| Journal | Journal of magnetism and magnetic materials |
| Volume | 310 |
| Issue number | 2 Suppl Part 2 |
| Publication status | Published - Mar 2007 |
| Peer-reviewed | Yes |
External IDs
| ORCID | /0000-0002-2391-6025/work/166325845 |
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Keywords
ASJC Scopus subject areas
Keywords
- Cerium, Iron, Magnetic structure, Neutron scattering, Rare earth compounds