Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Herbert C. Hoffmann; Silvia Paasch; Philipp Müller; Irena Senkovska; Mohan Padmanaban; Frank Glorius; Stefan Kaskel; Eike Brunner

doi:10.1039/c2cc35366k

Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

Herbert C. Hoffmann - , Chair of Bioanalytical Chemistry (Author)
Silvia Paasch - , Chair of Bioanalytical Chemistry (Author)
Philipp Müller - , University of Münster (Author)
Irena Senkovska - , Chair of Inorganic Chemistry I, University of Münster (Author)
Mohan Padmanaban - , University of Münster (Author)
Frank Glorius - , University of Münster (Author)
Stefan Kaskel - , Chair of Inorganic Chemistry I, University of Münster (Author)
Eike Brunner - , Chair of Bioanalytical Chemistry (Author)

Abstract

Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state¹³C NMR spectroscopy.

Details

Original language	English
Pages (from-to)	10484-10486
Number of pages	3
Journal	Chemical communications
Volume	48
Issue number	85
Publication status	Published - 1 Oct 2012
Peer-reviewed	Yes

External IDs

PubMed	22932689

Keywords

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Library keywords

542 Techniques, equipment & materials

Research Portal of the TU Dresden