Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy.
Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 10484-10486 |
| Seitenumfang | 3 |
| Fachzeitschrift | Chemical communications |
| Jahrgang | 48 |
| Ausgabenummer | 85 |
| Publikationsstatus | Veröffentlicht - 1 Okt. 2012 |
| Peer-Review-Status | Ja |
Externe IDs
| PubMed | 22932689 |
|---|