Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

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Contributors

  • Zheng Guo Lin - , Beijing Institute of Technology, Jacobs University Bremen (Author)
  • Lin Yuan Fan - , Beijing Institute of Technology (Author)
  • Aleksandar Kondinski - , Jacobs University Bremen, RWTH Aachen University (Author)
  • Nina Vankova - , Jacobs University Bremen, Leipzig University (Author)
  • Thomas Heine - , Jacobs University Bremen, Leipzig University (Author)
  • Bao Kuan Chen - , Beijing Institute of Technology (Author)
  • Ali Haider - , Jacobs University Bremen (Author)
  • Bo Wang - , Beijing Institute of Technology (Author)
  • Ulrich Kortz - , Jacobs University Bremen (Author)
  • Chang Wen Hu - , Beijing Institute of Technology (Author)

Abstract

The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

Details

Original languageEnglish
Pages (from-to)7811-7813
Number of pages3
JournalInorganic chemistry
Volume55
Issue number16
Publication statusPublished - 15 Aug 2016
Peer-reviewedYes
Externally publishedYes

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