Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 7811-7813 |
Seitenumfang | 3 |
Fachzeitschrift | Inorganic chemistry |
Jahrgang | 55 |
Ausgabenummer | 16 |
Publikationsstatus | Veröffentlicht - 15 Aug. 2016 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |