Bi4RuBr2 und Bi4RuI2: Zwei Varianten einer Kolumnarstruktur mit flächenverknüpften quadratischen [RuBi8/2]-Antiprismen
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Contributors
Abstract
Reaction of the elements yields black, lustrous, air insensitive crystals of the subhalides Bi4RuI2 (tetragonal, I4/m, a = 1183.9(2) pm, c = 669.7(2) pm. V = 938.66 ̇ 106 pm3) and Bi4RuBr2 (monoclinic, I112/m, a = 1211.9(2) pm, b = 1072.6(2) pm, c = 663.9(2) pm, y = 91.63(1)°, V = 862.64 ̇ 106pm3). The structures of the homöotypic compounds contain ∞1[RuBi8/2] strands of face-sharing square antiprisms. Halogen atoms lie above the edges of alternate Bi4 squares. Thereby chemical bonding differs significantly within the two types of Bi4 squares Though the Ru atoms on the central axis of the strand of antiprisms form pairs, extended Hückel calculations give no evidence of Ru-Ru bonds.
| Translated title of the contribution | Bi4RuBr2 and Bi4RuI2 Two varieties of a column structure with face-sharing [RuBi8/2] square antiprisms |
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Details
| Original language | German |
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| Pages (from-to) | 1583-1590 |
| Number of pages | 8 |
| Journal | Zeitschrift fur Anorganische und Allgemeine Chemie |
| Volume | 623 |
| Issue number | 10 |
| Publication status | Published - 1997 |
| Peer-reviewed | Yes |
| Externally published | Yes |
External IDs
| ORCID | /0000-0002-2391-6025/work/166325871 |
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Keywords
ASJC Scopus subject areas
Keywords
- Bismuth ruthenium bromide, Bismuth ruthenium iodide, Chemical bonding, Crystal structure, Subhalide