Bi24Ru3Br20: Ein pseudo-tetragonales subbromid mit [RuBi6Br12]-clustern und [Ru2Bi17Br4]-gruppen
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
The melting reaction of Ru with Bi and BiBr yields black, lustrous, air insensitive crystals of the subbromide Bi24Ru3Br20. The orthorhombic crystal structure (space group Pc21n, a = b = 1377.8(1) pm, c = 3222.3(4) pm, V = 6117.0 ̇ 106pm3) deceives pseudo-symmetry with respect to the tetragonal space group P4/ncc leading to multiply twinned crystals. The structure can formally be subdivided in [RuBi6Br12] clusters, [Ru2Bi17Br4] stacks, and [BiBr4] groups.
| Translated title of the contribution | Bi24Ru3Br20 A pseudo-tetragonal structure with [RuBi6Br12] clusters and [Ru2Bi17Br4] groups |
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Details
| Original language | German |
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| Pages (from-to) | 1591-1598 |
| Number of pages | 8 |
| Journal | Zeitschrift fur Anorganische und Allgemeine Chemie |
| Volume | 623 |
| Issue number | 10 |
| Publication status | Published - 1997 |
| Peer-reviewed | Yes |
| Externally published | Yes |
External IDs
| ORCID | /0000-0002-2391-6025/work/166325844 |
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Keywords
ASJC Scopus subject areas
Keywords
- Bismuth ruthenium bromide, Cluster, Crystal structure, Pseudo-symmetry, Subhalide, Twinning