Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
The defined Fe hydride complex FeH(CO)(NO)(Ph3P)2 is highly active as a catalyst for selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane employed either E- or Z-selective hydrosilylation products were formed in excellent yields and good to excellent stereoselectivities.
Details
| Original language | English |
|---|---|
| Pages (from-to) | 5419-5421 |
| Journal | Chemical communications |
| Volume | 48 |
| Issue number | 44 |
| Publication status | Published - 2012 |
| Peer-reviewed | Yes |
External IDs
| Scopus | 84861633841 |
|---|---|
| ORCID | /0000-0001-8423-6173/work/142250806 |