Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
The defined Fe hydride complex FeH(CO)(NO)(Ph3P)2 is highly active as a catalyst for selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane employed either E- or Z-selective hydrosilylation products were formed in excellent yields and good to excellent stereoselectivities.
Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 5419-5421 |
| Fachzeitschrift | Chemical communications |
| Jahrgang | 48 |
| Ausgabenummer | 44 |
| Publikationsstatus | Veröffentlicht - 2012 |
| Peer-Review-Status | Ja |
Externe IDs
| Scopus | 84861633841 |
|---|---|
| ORCID | /0000-0001-8423-6173/work/142250806 |