An approach to hyperbranched polymers with a degree of branching of 100%

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • G Maier - (Author)
  • C Zech - (Author)
  • B. Voit - , Leibniz Institute of Polymer Research Dresden (Author)
  • H Komber - (Author)

Abstract

General guidelines for the design of monomers for the synthesis of hyperbranched polymers without linear units are presented. The synthesis of one monomer fulfilling these requirements and the first results of the polymerization of this monomer are described. 4-(3-Maleimidopropoxy)-4'-methoxybenzaldehyde azine was used as a monomer of the AB(2)-type in a "criss-cross" cycloaddition with the maleimide group as A-function and the azine as two B-groups. Melt condensation of this monomer gave a polymer ((M) over bar(n) = 5700) which showed H-1 and C-13 NMR spectra corresponding well to the expected completely branched structure.

Details

Original languageEnglish
Pages (from-to)2655-2664
Number of pages10
JournalMacromolecular chemistry and physics : MCP
Volume199
Issue number12
Publication statusPublished - Dec 1998
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 0001494711
ORCID /0000-0002-4531-691X/work/148607632

Keywords

Keywords

  • Hexafluoroacetone azine, 3+2 cycloaddition, Polymerization, Polyesters, <3+2>-cycloaddition