An approach to hyperbranched polymers with a degree of branching of 100%

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • G Maier - (Autor:in)
  • C Zech - (Autor:in)
  • B. Voit - , Leibniz Institute of Polymer Research Dresden (Autor:in)
  • H Komber - (Autor:in)

Abstract

General guidelines for the design of monomers for the synthesis of hyperbranched polymers without linear units are presented. The synthesis of one monomer fulfilling these requirements and the first results of the polymerization of this monomer are described. 4-(3-Maleimidopropoxy)-4'-methoxybenzaldehyde azine was used as a monomer of the AB(2)-type in a "criss-cross" cycloaddition with the maleimide group as A-function and the azine as two B-groups. Melt condensation of this monomer gave a polymer ((M) over bar(n) = 5700) which showed H-1 and C-13 NMR spectra corresponding well to the expected completely branched structure.

Details

OriginalspracheEnglisch
Seiten (von - bis)2655-2664
Seitenumfang10
FachzeitschriftMacromolecular chemistry and physics : MCP
Jahrgang199
Ausgabenummer12
PublikationsstatusVeröffentlicht - Dez. 1998
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 0001494711
ORCID /0000-0002-4531-691X/work/148607632

Schlagworte

Schlagwörter

  • Hexafluoroacetone azine, 3+2 cycloaddition, Polymerization, Polyesters, <3+2>-cycloaddition