Al2O3-TiOx as full area passivating contacts for silicon surfaces utilizing oxygen scavenging titanium interlayers

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Full area transparent contacts are the next step in order to enhance the efficiency of silicon based passivated emitter rear cells. Here we present a full area contact based on Al2O3 and reduced TiOx. The thin Al2O3 acts as passivating tunneling layer, whereas the TiOx is used for charge carrier transport. This work provides a way to enhance the conductivity of TiOx by forming gas annealing (FGA) and doping with tantalum. Furthermore, it addresses the native SiOx without chemical treatment. A thin titanium interlayer (Ti-IL) serves this purpose. Current-voltage measurements reveal a contact resistance of 30 Ωcm2 for 50 nm of pure TiOx. Ta-doping combined with a 6 nm thick Ti-IL reduces the contact resistance by two orders of magnitude down to 0.36 Ωcm2. The passivation by an Al2O3/TiOx layer stack leads to an excellent surface recombination velocity (SRV) of 5.6 cm/s with only 3 nm Al2O3 but results in a large contact resistance of about 100 Ωcm2. This contact resistance can be reduced by three orders of magnitude down to 0.25 Ωcm2 including a 10 nm Ti-IL while still providing a sufficient SRV of about 60 cm/s. The absorption coefficient of 6.3×105 cm−1 inhibits the usage as front contact for solar cells. However, it could be used as a backside contact, since the transmission is less important on the backside of a monofacial solar cell.

Details

Original languageEnglish
Article number110651
JournalSolar energy materials and solar cells
Volume215
Publication statusPublished - 15 Sept 2020
Peer-reviewedYes

External IDs

ORCID /0000-0003-3814-0378/work/142256212

Keywords

Sustainable Development Goals

Keywords

  • AlO, Conductive passivation, Doped TiO, Full area contacts, PERC, Silicon solar cell