A novel coordination mode of 7-methyl-7-sila-nido-undecaborate(1-)

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Lars Wesemann - , RWTH Aachen University (Author)
  • Michael Trinkaus - , RWTH Aachen University (Author)
  • Michael Ruck - , Karlsruhe Institute of Technology (Author)

Abstract

B-N-M bridges, resulting from the activation of two B,H units, are present in the anion [Nb(MeSiB10H8)(μ-NMe2)2Br3]- (see structure depicted). Thus, this is an example for a hitherto unknown coordination mode in the chemistry of heteroborane clusters.

Details

Original languageEnglish
Pages (from-to)2375-2377
Number of pages3
JournalAngewandte Chemie - International Edition
Volume38
Issue number16
Publication statusPublished - 12 Aug 1999
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0002-2391-6025/work/166325863

Keywords

ASJC Scopus subject areas

Keywords

  • Boranes, Cluster compounds, Niobium, Si ligands, Tantalum