A Nanocar and Rotor in One Molecule

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Depending on its adsorption conformation on the Au(111) surface, a zwitterionic single-molecule machine works in two different ways under bias voltage pulses. It is a unidirectional rotor while anchored on the surface. It is a fast-drivable molecule vehicle (nanocar) while physisorbed. By tuning the surface coverage, the conformation of the molecule can be selected to be either rotor or nanocar. The inelastic tunneling excitation producing the movement is investigated in the same experimental conditions for both the unidirectional rotation of the rotor and the directed movement of the nanocar.

Details

Original languageEnglish
Pages (from-to)3128-3134
Number of pages7
JournalACS nano
Volume17
Issue number3
Publication statusPublished - 14 Feb 2023
Peer-reviewedYes

External IDs

PubMed 36638056
WOS 000920378300001
ORCID /0000-0001-9607-8715/work/142252652

Keywords

Keywords

  • density functional theory, inelastic tunneling electrons, molecular manipulation, molecule rotor, nanocar, scanning tunneling microscopy, Scanning tunneling microscopy, Molecular manipulation, Density functional theory, Molecule rotor, Inelastic tunneling electrons, Nanocar