What is the speed limit of martensitic transformations?

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Stefan Schwabe - , Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • Klara Lünser - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Daniel Schmidt - , Leibniz Institute for Crystal Growth, TXproducts UG (Author)
  • Kornelius Nielsch - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • Peter Gaal - , Leibniz Institute for Crystal Growth, TXproducts UG (Author)
  • Sebastian Fähler - , Helmholtz-Zentrum Dresden-Rossendorf (Author)

Abstract

Structural martensitic transformations enable various applications, which range from high stroke actuation and sensing to energy efficient magnetocaloric refrigeration and thermomagnetic energy harvesting. All these emerging applications benefit from a fast transformation, but up to now their speed limit has not been explored. Here, we demonstrate that a thermoelastic martensite to austenite transformation can be completed within 10 ns. We heat epitaxial Ni-Mn-Ga films with a nanosecond laser pulse and use synchrotron diffraction to probe the influence of initial temperature and overheating on transformation rate and ratio. We demonstrate that an increase in thermal energy drives this transformation faster. Though the observed speed limit of 2.5 × 1027 (Js)1 per unit cell leaves plenty of room for further acceleration of applications, our analysis reveals that the practical limit will be the energy required for switching. Thus, martensitic transformations obey similar speed limits as in microelectronics, as expressed by the Margolus–Levitin theorem.

Details

Original languageEnglish
Pages (from-to)633-641
Number of pages9
JournalScience and technology of advanced materials
Volume23
Issue number1
Publication statusPublished - 2022
Peer-reviewedYes

Keywords

ASJC Scopus subject areas

Keywords

  • magnetocaloric refrigeration, Martensitic phase transitions, shape memory alloys, thermomagnetic energy harvesting, time-resolved synchrotron diffraction