Urban soundscapes are complex due to the interaction of different sound sources and the influence of structures on sound propagation. Moreover, the dynamic nature of sounds over time and space adds to this complexity. Virtual reality (VR) has emerged as a powerful tool to simulate acoustic and visual environments, offering users an immersive sense of presence in controlled settings. This technology facilitates more accurate and predictive assessment of urban environments. It serves as a flexible tool for exploring, analyzing, and interpreting them under repeatable conditions. This study presents a systematic literature review focusing on research that integrates VR technology for the audiovisual reconstruction of urban environments. This topic remains relatively underrepresented in the existing literature. A total of 69 peer-reviewed studies were analyzed in this systematic review. The studies were classified according to research goals, selected urban environments, VR technologies used, technical equipment, and experimental setups. In this study, the relationship between the tools used in urban VR representations is examined, and experimental setups are discussed from both technical and perceptual perspectives. This paper highlights existing challenges and opportunities in using VR to assess soundscapes and offers practical insights for future applications of VR in urban environments.