Utilizing Electronic Resistance Measurement for Tailoring Lithium-Ion Battery Cathode Formulations

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Christoph Seidl - , Chair of Inorganic Non-Metallic Materials, Mercedes-Benz Group AG (Author)
  • Sören Thieme - , Mercedes-Benz Group AG (Author)
  • Martin Frey - , Mercedes-Benz Group AG (Author)
  • Kristian Nikolowski - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Alexander Michaelis - , Chair of Inorganic Non-Metallic Materials, Fraunhofer Institute for Ceramic Technologies and Systems (Author)

Abstract

Cathode formulation, which describes the amount of cathode active material (CAM), conductive additives (CAs), and binder within a cathode compound, is decisive for the performance metrics of lithium-ion battery (LIB) cells. The direct measurement of electronic resistance can be an enabler for more time- and cost-efficient cathode formulation improvements. Within this work, we correlate the electronic resistance with the electrochemical performance of cathodes. Two different high Nickel NCM cathode materials and numerous CAs are used to validate the findings. A detailed look into the resistance reduction potential of carbon black (CB) and single-walled carbon nanotubes (SWCNT) and their mixtures is made. Finally, an impact estimation of cathode formulation changes on LIB key performance factors, such as energy density and cost, is shown.

Details

Original languageEnglish
Article number227
JournalBatteries
Volume10
Issue number7
Publication statusPublished - Jul 2024
Peer-reviewedYes

Keywords

Sustainable Development Goals

Keywords

  • cathode, conductive additives, contact resistance, electrode characterisation methods, electronic limitations, lithium-ion battery