Unidirectional diagonal order and three-dimensional stacking of charge stripes in orthorhombic Pr1.67Sr0.33NiO4 and Nd1.67 Sr0.33 NiO4
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Contributors
Abstract
The interplay between crystal symmetry and charge stripe order in Pr1.67 Sr0.33 Ni O4 and Nd1.67 Sr0.33 Ni O4 has been studied by means of single crystal x-ray diffraction. In contrast to tetragonal La1.67 Sr0.33 Ni O4, these crystals are orthorhombic. The corresponding distortion of the Ni O2 planes is found to dictate the direction of the charge stripes, similar to the case of diagonal spin stripes in the insulating phase of La2-x Srx Cu O4. In particular, diagonal stripes seem to always run along the short a axis, which is the direction of the octahedral tilt axis. In contrast, no influence of the crystal symmetry on the charge stripe ordering temperature itself was observed, with TCO ∼240 K for La, Pr, and Nd. The coupling between lattice and stripe degrees of freedom allows one to produce macroscopic samples with unidirectional stripe order. In samples with stoichiometric oxygen content and a hole concentration of exactly 1/3, charge stripes exhibit a staggered stacking order with a period of three Ni O2 layers, previously only observed with electron microscopy in domains of mesoscopic dimensions. Remarkably, this stacking order starts to melt about 40 K below TCO. The melting process can be described by mixing the ground state, which has a three-layer stacking period, with an increasing volume fraction with a two-layer stacking period.
Details
Original language | English |
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Article number | 085112 |
Journal | Physical Review B - Condensed Matter and Materials Physics |
Volume | 74 |
Issue number | 8 |
Publication status | Published - 2006 |
Peer-reviewed | Yes |
External IDs
ORCID | /0000-0002-2438-0672/work/159172188 |
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