Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System
Research output: Contribution to journal › Review article › Contributed › peer-review
Contributors
Abstract
Flexible porous frameworks are at the forefront of materials research. A unique feature is their ability to open and close their pores in an adaptive manner induced by chemical and physical stimuli. Such enzyme-like selective recognition offers a wide range of functions ranging from gas storage and separation to sensing, actuation, mechanical energy storage and catalysis. However, the factors affecting switchability are poorly understood. In particular, the role of building blocks, as well as secondary factors (crystal size, defects, cooperativity) and the role of host–guest interactions, profit from systematic investigations of an idealized model by advanced analytical techniques and simulations. The review describes an integrated approach targeting the deliberate design of pillared layer metal–organic frameworks as idealized model materials for the analysis of critical factors affecting framework dynamics and summarizes the resulting progress in their understanding and application.
Details
Original language | English |
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Article number | e202218076 |
Number of pages | 48 |
Journal | Angewandte Chemie - International Edition |
Volume | 62 |
Issue number | 33 |
Publication status | Published - 11 May 2023 |
Peer-reviewed | Yes |
External IDs
WOS | 000984940300001 |
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Keywords
ASJC Scopus subject areas
Keywords
- Flexibility Control, Paddle Wheel, Pillared Layer MOFs, Surface, Switchability