Ultra-high strength Co–Ta–B bulk metallic glasses: Glass formation, thermal stability and crystallization

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Ju Wang - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Ivan Kaban - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Volodymyr Levytskyi - , Freiberg University of Mining and Technology (Author)
  • Ran Li - , Beihang University (Author)
  • Junhee Han - , Leibniz Institute for Solid State and Materials Research Dresden, Korea Institute of Industrial Technology (Author)
  • Mihai Stoica - , ETH Zurich (Author)
  • Roman Gumeniuk - , Freiberg University of Mining and Technology (Author)
  • Kornelius Nielsch - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

Co61Ta6B33, Co59Ta8B33, Co57Ta10B33 and Co53Ta10B37 bulk metallic glasses (BMGs) exhibit a good combination of the ultra-high fracture strength in the range of about 5.4–6.2 GPa, Vickers hardness of 1459–1653 HV0.2 and plastic strain of 0.3–3.2%, depending on composition. Glass forming-ability and physical properties of Co–Ta–B BMGs are discussed in relationship to the Ta and B content and atomic structure. Crystallization upon isochronal and isothermal annealing is studied using differential scanning calorimetry and X-ray diffraction. A novel crystalline phase with ~Ta2Co15B8 or ~TaCo7B4 formula is shown to form upon glass annealing. The incubation time for isothermal crystallization in the supercooled liquid state near Tg is supposed to be sufficient for thermoplastic forming of Co–Ta–B BMGs.

Details

Original languageEnglish
Article number158398
JournalJournal of alloys and compounds
Volume860
Publication statusPublished - 15 Apr 2021
Peer-reviewedYes

Keywords

Keywords

  • Bulk metallic glass, Co–Ta–B, Crystallization kinetics, Thermal properties, Ultra-high strength