Tuning the interactions in the spin-ice materials Dy2Ge2-xSixO7 by silicon substitution

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Contributors

Abstract

We report that the lattice constant of Dy2Ge2-xSixO7 (x=0, 0.02, 0.08, 0.125) can be systematically reduced by substituting the nonmagnetic germanium ion in the cubic pyrochlore oxide with silicon. A multianvil high-pressure synthesis was performed up to 16 GPa and 1100°C to obtain polycrystalline samples in a solid-state reaction. Measurements of magnetization, ac susceptibility, and heat capacity reveal the typical signatures of a spin-ice phase. From the temperature shift of the peaks, observed in the temperature-dependent heat capacity, we deduce an increase in the strength of the exchange interaction. In conclusion, the reduced lattice constant leads to a changed ratio of the competing exchange and dipolar interaction. This puts the new spin-ice compounds closer towards the phase boundary of a short-range spin-ice arrangement and antiferromagnetic long-range order consistent with an observed reduction in the energy scale of monopole excitations.

Details

Original languageEnglish
Article number054403
JournalPhysical Review B
Volume100
Issue number5
Publication statusPublished - 1 Aug 2019
Peer-reviewedYes