Thermo-Responsive Nanogels Based on Poly[NIPAAm-graft-(2-alkyl-2-oxazoline)]s Crosslinked in the Micellar State
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Graft copolymers with thermo-sensitive PNIPAAm backbone and hydrophilic PEtOxa graft chains demonstrated typical amphiphilic behavior. For specific compositions stable micelle-like aggregates were formed depending on the temperature. Applying long polyoxazoline side chains ((DP) over bar > 120), stable reversible micelle-like aggregates with hydrodynamic radii of 30- 40 nm could be obtained between 33 and 55 degrees C. These graft copolymers have been successfully crosslinked by electron-beam irradiation in the micellar state yielding core/shell type nanogels with thermo-reversible swelling behavior. The temperature dependent volume change of the new thermo-responsive nanogels due to the phase transition of the PNIPAAm core has been verified by DLS.
Details
Original language | English |
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Pages (from-to) | 1035-1042 |
Number of pages | 8 |
Journal | Macromolecular chemistry and physics : MCP |
Volume | 211 |
Issue number | 9 |
Publication status | Published - 3 May 2010 |
Peer-reviewed | Yes |
External IDs
Scopus | 77951799631 |
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ORCID | /0000-0002-4531-691X/work/148607812 |
Keywords
Keywords
- Crosslinking, Electron beam irradiation, Graft copolymers, Self-organization, Stimuli-sensitive polymers