Thermo-Responsive Nanogels Based on Poly[NIPAAm-graft-(2-alkyl-2-oxazoline)]s Crosslinked in the Micellar State

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Stefan Zschoche - , Leibniz Institute of Polymer Research Dresden (Author)
  • Juan Rueda - , Pontificia Universidad Católica del Perú (Author)
  • Volodymyr Boyko - , BASF (Author)
  • Franziska Krahl - , TUD Dresden University of Technology (Author)
  • Karl-Friedrich Arndt - , Chair of Special Physical Chemistry/Physical Chemistry of Polymers (Author)
  • Brigitte Voit - , Leibniz Institute of Polymer Research Dresden (Author)

Abstract

Graft copolymers with thermo-sensitive PNIPAAm backbone and hydrophilic PEtOxa graft chains demonstrated typical amphiphilic behavior. For specific compositions stable micelle-like aggregates were formed depending on the temperature. Applying long polyoxazoline side chains ((DP) over bar > 120), stable reversible micelle-like aggregates with hydrodynamic radii of 30- 40 nm could be obtained between 33 and 55 degrees C. These graft copolymers have been successfully crosslinked by electron-beam irradiation in the micellar state yielding core/shell type nanogels with thermo-reversible swelling behavior. The temperature dependent volume change of the new thermo-responsive nanogels due to the phase transition of the PNIPAAm core has been verified by DLS.

Details

Original languageEnglish
Pages (from-to)1035-1042
Number of pages8
JournalMacromolecular chemistry and physics : MCP
Volume211
Issue number9
Publication statusPublished - 3 May 2010
Peer-reviewedYes

External IDs

Scopus 77951799631
ORCID /0000-0002-4531-691X/work/148607812

Keywords

Keywords

  • Crosslinking, Electron beam irradiation, Graft copolymers, Self-organization, Stimuli-sensitive polymers