The thermocapillary effect on gas bubbles growing on electrodes of different sizes

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Syed Sahil Hossain - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Gerd Mutschke - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Aleksandr Bashkatov - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Kerstin Eckert - , Chair of Transport Processes at Interfaces, Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)

Abstract

Recently, the strongly inhomogeneous current density occurring near a microelectrode was identified as driving a thermocapillary electrolyte flow near gas bubbles growing during electrolysis (Massing et al., 2019) [1]. The present paper is investigating this effect in more detail under various operating conditions. Furthermore, by simplified modeling, the question is answered of whether this effect is also of importance at large planar electrodes. The direction of the thermocapillary force on the bubble is found to change from retarding to advancing the bubble release when the size of the electrode is increased. Conclusions are drawn on how the thermocapillary effect at planar electrodes depends on the electrode coverage and the bubble departure size, also considering industrially relevant values of the current density.

Details

Original languageEnglish
Article number136461
JournalElectrochimica acta
Volume353
Publication statusPublished - 1 Sept 2020
Peer-reviewedYes

Keywords

Keywords

  • Electrolysis, Hydrogen evolution, Macroelectrode, Marangoni force, Microelectrode, Thermocapillarity