The stepped reaction of decafluorobiphenyl with thiophenol studied by in situ F-19 NMR spectroscopy
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Kinetic studies on the reaction of decafluorobiphenyl and di- and tetra(phenylthio)-substituted perfluorobiphenyl with thiophenol in the presence of triethylamine were performed by in situ F-19 NMR spectroscopy to determine rate constants. In well-defined consecutive reactions, the even-numbered phenylthio derivatives are main products whereas the odd-numbered derivatives are much more reactive and were observed only in low concentrations. Very pronounced differences in rate constants and reactivity were obtained. (C) 2013 Elsevier B.V. All rights reserved.
Details
Original language | English |
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Pages (from-to) | 314-321 |
Number of pages | 8 |
Journal | Journal of Fluorine Chemistry |
Volume | 156 |
Publication status | Published - Dec 2013 |
Peer-reviewed | Yes |
External IDs
Scopus | 84889095948 |
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ORCID | /0000-0002-4531-691X/work/148607902 |
Keywords
Keywords
- Decafluorobiphenyl, F-19 nmr, Kinetics, Nucleophilic substitution, Thiophenol