The effect of tuning the microstructure of TIPS-tetraazapentacene on the performance of solution processed thin film transistors

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Fabian Paulus - , Heidelberg University  (Author)
  • Jens U. Engelhart - , Heidelberg University  (Author)
  • Paul E. Hopkinson - , Heidelberg University  (Author)
  • Christian Schimpf - , Freiberg University of Mining and Technology (Author)
  • Andreas Leineweber - , Freiberg University of Mining and Technology (Author)
  • Henning Sirringhaus - , University of Cambridge (Author)
  • Yana Vaynzof - , Heidelberg University  (Author)
  • Uwe H.F. Bunz - , Heidelberg University , University of Cambridge (Author)

Abstract

We report a comprehensive study of the symmetrical 6,13-bis(triisopropylsilylethynyl)tetraazapentacene (TIPS-TAP) used as an electron transporting material in organic field-effect transistors. We study the optical, electronic, structural and morphological properties of thin films of TIPS-TAP as deposited by spin-coating and zone-casting techniques. Depending on the solution processing conditions and procedures we find a variety of microstructures for TIPS-TAP ranging from highly polycrystalline to well-aligned crystalline films. Field-effect transistors are fabricated in two different architectures to evaluate the charge transport properties of TIPS-TAP in such films, and bias-stress experiments reveal a good electric stability of TIPS-TAP. The extracted electron mobilities vary over several orders of magnitude depending on the resulting morphology of the active layer reaching a maximum of 0.42 cm2 V-1 s-1 for uniaxial aligned crystallites in zone-cast transistors.

Details

Original languageEnglish
Pages (from-to)1194-1200
Number of pages7
JournalJournal of Materials Chemistry C
Volume4
Issue number6
Publication statusPublished - 2016
Peer-reviewedYes
Externally publishedYes