Temperature-controlled coalescence during the growth of Ge crystals on deeply patterned Si substrates
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
A method for growing suspended Ge films on micron -sized Si pillars in Si(001) is discussed. In [C.V. Falub et al., Science 335 (2012) 1330] vertically aligned three-dimensional Ge crystals, separated by a few tens of nanometers, were obtained by depositing several micrometers of Ge using Low-Energy Plasma-Enhanced Chemical Vapor Deposition. Here a different regime of high growth temperature is exploited in order to induce the merging of the crystals into a connected structure eventually forming a continuous, two-dimensional film. The mechanisms leading to such a behavior are discussed with the aid of an effective model of crystal growth. Both the effects of deposition and curvature-driven surface diffusion are considered to reproduce the main features of coalescence. The key enabling role of high temperature is identified with the activation of the diffusion process on a time scale competitive with the deposition rate. We demonstrate the versatility of the deposition process, which allows to switch between the formation of individual crystals and a continuous suspended film simply by tuning the growth temperature. (C) 2016 Elsevier B.V. All rights reserved.
Details
Original language | English |
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Pages (from-to) | 86-95 |
Number of pages | 10 |
Journal | Journal of crystal growth |
Volume | 440 |
Publication status | Published - 15 Apr 2016 |
Peer-reviewed | Yes |
Externally published | Yes |
External IDs
Scopus | 84958751681 |
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ORCID | /0000-0002-4217-0951/work/142237434 |
Keywords
Keywords
- Growth models, Chemical vapor deposition processes, Semiconducting germanium, Semiconducting silicon, PENDEO-EPITAXIAL GROWTH, GALLIUM NITRIDE, THIN-FILMS, LAYERS, EVOLUTION, HETEROEPITAXY, INTEGRATION, MODEL