Synthesis of multifunctional coupling agents and their selective reactions with hydroxy and amino groups in the melt

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Haiping Zhang - , Leibniz Institute of Polymer Research Dresden (Author)
  • Lothar Jakisch - , Leibniz Institute of Polymer Research Dresden (Author)
  • Hartmut Komber - , Leibniz Institute of Polymer Research Dresden (Author)
  • Brigitte Voit - , Chair of Organic Chemistry of Polymers, Leibniz Institute of Polymer Research Dresden (Author)
  • Frank Boehme - , Leibniz Institute of Polymer Research Dresden (Author)

Abstract

Three new coupling agents with different numbers of N-acyl lactam and 4H-3,1-benzoxazin-4-one groups were synthesized. A selective stepwise conversion of the coupling agents with 1-dodecanol and 1-dodecylamine was demonstrated by means of solvent-free model reactions in melt at 195 and 210 C, respectively. These coupling agents are regarded as potential cores for the synthesis of novel starlike compounds and polymers with defined arms varying in type and lengths. (C) 2013 Elsevier Ltd. All rights reserved.

Details

Original languageEnglish
Pages (from-to)3656-3663
Number of pages8
JournalTetrahedron
Volume69
Issue number18
Publication statusPublished - 6 May 2013
Peer-reviewedYes

External IDs

Scopus 84875464039
ORCID /0000-0002-4531-691X/work/148607891

Keywords

Keywords

  • Benzoxazinone, Coupling reactions, N-Acyllactam

Library keywords