Synthesis of highly electrochemically active Li2S nanoparticles for lithium-sulfur-batteries

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • M. Kohl - , Fraunhofer Institute for Material and Beam Technology (Author)
  • J. Brückner - , Fraunhofer Institute for Material and Beam Technology (Author)
  • I. Bauer - , Fraunhofer Institute for Material and Beam Technology (Author)
  • H. Althues - , Fraunhofer Institute for Material and Beam Technology (Author)
  • S. Kaskel - , Chair of Inorganic Chemistry I, Fraunhofer Institute for Material and Beam Technology (Author)

Abstract

Carbothermal reduction of lithium sulfate below its melting point was used to produce sub-micron sized lithium sulfide particles which retain the morphology of the source particle. Using a lithium polysulfide-doped ether electrolyte, significantly enhanced activation of lithium sulfide could be accomplished in battery cells, achieving high discharge capacities up to 1360 mA h gsulfur-1 at a 0.1C rate. Showing an economically viable and scalable reaction routine for future lithium-sulfur-batteries.

Details

Original languageEnglish
Pages (from-to)16307-16312
Number of pages6
JournalJournal of Materials Chemistry. A, Materials for energy and sustainability
Volume3
Issue number31
Publication statusPublished - 21 Aug 2015
Peer-reviewedYes