Synthesis of Anionic Iron Polyphosphides by Reaction of White Phosphorus with "Cp*Fe-"
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Transforming P4: The reaction of the anionic Cp*Fe− equivalent 1 with white phosphorus is a promising new approach toward P4 activation. The reaction proceeded under mild conditions and enabled the synthesis of remarkable anionic polyphosphido complexes. Two new iron polyphosphides 2 and 3 were isolated and characterized by X-ray crystallography, 31P NMR spectroscopy, and quantum chemical calculations.
Details
| Original language | English |
|---|---|
| Journal | Angewandte Chemie International Edition |
| Volume | 50 |
| Issue number | 29 |
| Publication status | Published - 2011 |
| Peer-reviewed | Yes |
External IDs
| WOS | 000292644400041 |
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| Scopus | 79960023281 |