Synthesis and Characterization of Stiff, Self-Crosslinked Thermoresponsive DMAA Hydrogels

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Juan Carlos Rueda - , Pontificia Universidad Católica del Perú (Author)
  • Fatima Santillan - , Pontificia Universidad Católica del Perú (Author)
  • Hartmut Komber - , Leibniz Institute of Polymer Research Dresden (Author)
  • Brigitte Voit - , Leibniz Institute of Polymer Research Dresden (Author)

Abstract

Stiff thermosensitive hydrogels (HG) were synthesized by self-crosslinking free radical polymerization of N,N-dimethylacrylamide (DMAA) and N-isopropylacrylamide (NIPAAm), adjusting the degree of swelling by carboxylate-containing sodium acrylate (NaAc) or a 2-oxazoline macromonomer (MM). The formation of hydrogels was possible due to the self-crosslinking property of DMAA when polymerized with peroxodisulfate initiator type. The MM was synthetized by the ring-opening cationic polymerization of 2-methyl-2-oxazoline (MeOxa) and methyl-3-(oxazol-2-yl)-propionate (EsterOxa), and contained a polymerizable styryl endgroup. After ester hydrolysis of EsterOxa units, a carboxylate-containing MM was obtained. The structure of the hydrogels was confirmed by H-1 high-resolution (HR)-MAS NMR spectroscopy. Suitable conditions and compositions of the comonomers have been found, which allowed efficient self-crosslinking as well as a thermoresponsive swelling in water. Incorporation of both the polar comonomer and the macromonomer, in small amounts furthermore allowed the adjustment of the degree of swelling. However, the macromonomer was better suited to retain the thermoresponsive behavior of the poly (NIPAAm) due to a phase separation of the tangling polyoxazoline side chains. Thermogravimetric analysis determined that the hydrogels were stable up to similar to 350 degrees C, and dynamic mechanical analysis characterized a viscoelastic behavior of the hydrogels, properties that are required, for example, for possible use as an actuator material.

Details

Original languageEnglish
Article number1401
Number of pages16
JournalPolymers
Volume12
Issue number6
Publication statusPublished - Jun 2020
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 32580475
Scopus 85087794289
ORCID /0000-0002-4531-691X/work/194254553

Keywords

Keywords

  • DMAA hydrogel, Macromondomer, Polyoxazoline, Self-crosslinking, Thermosensitivity