Synthesis and characterization of Pt(ii) and Au(i) complexes with N-oxy-heterocyclic carbene ligands (NOHCs)

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Two N-alkyloxy-N′-phenylimidazolium proligands and the corresponding platinum(ii) cyclometalated N-alkyloxyimidazol-2-ylidene complexes with β-diketonate auxiliary ligands, [(CNOHC^C*)Pt(L∩L)] (L∩L = acetyacetonate (acac) or 1,3-bis(2,4,6-trimethylphenyl)-propane-1,3-dionato (mesacac)) were synthesized and fully characterized. In addition, a Au(i) monocarbene complex was synthesized, isolated and characterized. Solid-state structures of two cyclometalated platinum(ii) NOHC complexes and the Au(i) NOHC complex were obtained providing structural proof.

Details

Original languageEnglish
Pages (from-to)9323-9329
Number of pages7
JournalDalton transactions
Volume53
Issue number22
Publication statusPublished - 15 May 2024
Peer-reviewedYes

External IDs

PubMed 38747257

Keywords

ASJC Scopus subject areas