Synthesis and characterization of Pt(ii) and Au(i) complexes with N-oxy-heterocyclic carbene ligands (NOHCs)
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Two N-alkyloxy-N′-phenylimidazolium proligands and the corresponding platinum(ii) cyclometalated N-alkyloxyimidazol-2-ylidene complexes with β-diketonate auxiliary ligands, [(CNOHC^C*)Pt(L∩L)] (L∩L = acetyacetonate (acac) or 1,3-bis(2,4,6-trimethylphenyl)-propane-1,3-dionato (mesacac)) were synthesized and fully characterized. In addition, a Au(i) monocarbene complex was synthesized, isolated and characterized. Solid-state structures of two cyclometalated platinum(ii) NOHC complexes and the Au(i) NOHC complex were obtained providing structural proof.
Details
Original language | English |
---|---|
Pages (from-to) | 9323-9329 |
Number of pages | 7 |
Journal | Dalton transactions |
Volume | 53 |
Issue number | 22 |
Publication status | Published - 15 May 2024 |
Peer-reviewed | Yes |
External IDs
PubMed | 38747257 |
---|