Sub-picosecond charge-transfer at near-zero driving force in polymer:non-fullerene acceptor blends and bilayers

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Yufei Zhong - , University of Bern (Author)
  • Martina Causa’ - , University of Bern (Author)
  • Gareth John Moore - , University of Bern (Author)
  • Philipp Krauspe - , University of Bern (Author)
  • Bo Xiao - , Chinese Academy of Sciences (Author)
  • Florian Günther - , Universidade de São Paulo (Author)
  • Jonas Kublitski - , Chair of Opto-Electronics (Author)
  • Rishi Shivhare - , Chair of Organic Devices (cfaed) (Author)
  • Johannes Benduhn - , Chair of Opto-Electronics (Author)
  • Eyal BarOr - , University of Potsdam (Author)
  • Subhrangsu Mukherjee - , National Institute of Standards and Technology (NIST) (Author)
  • Kaila M. Yallum - , University of Bern (Author)
  • Julien Réhault - , University of Bern (Author)
  • Stefan C. B. Mannsfeld - , Chair of Organic Devices (cfaed) (Author)
  • Dieter Neher - , University of Potsdam (Author)
  • Lee J. Richter - , National Institute of Standards and Technology (NIST) (Author)
  • Dean M. DeLongchamp - , National Institute of Standards and Technology (NIST) (Author)
  • Frank Ortmann - , Computational Nanoelectronics (Junior Research Group) (cfaed) (Author)
  • Koen Vandewal - , Hasselt University (Author)
  • Erjun Zhou - , Chinese Academy of Sciences (Author)
  • Natalie Banerji - , University of Bern (Author)

Abstract

Organic photovoltaics based on non-fullerene acceptors (NFAs) show record efficiency of 16 to 17% and increased photovoltage owing to the low driving force for interfacial charge-transfer. However, the low driving force potentially slows down charge generation, leading to a tradeoff between voltage and current. Here, we disentangle the intrinsic charge-transfer rates from morphology-dependent exciton diffusion for a series of polymer:NFA systems. Moreover, we establish the influence of the interfacial energetics on the electron and hole transfer rates separately. We demonstrate that charge-transfer timescales remain at a few hundred femtoseconds even at near-zero driving force, which is consistent with the rates predicted by Marcus theory in the normal region, at moderate electronic coupling and at low re-organization energy. Thus, in the design of highly efficient devices, the energy offset at the donor:acceptor interface can be minimized without jeopardizing the charge-transfer rate and without concerns about a current-voltage tradeoff.

Details

Original languageEnglish
Article number833
JournalNature communications
Volume11
Publication statusPublished - Dec 2020
Peer-reviewedYes

External IDs

Scopus 85079335152

Keywords