Spatiotemporal Distribution and Source Apportionment of Suspended Polycyclic Aromatic Hydrocarbons in Surface Water

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Ke Xing Peng - , Jinan University (Author)
  • Rui Fei Li - , Institute of Urban and Industrial Water Management (Author)
  • Yi Chen Zhou - , Jinan University (Author)
  • Ze Ming Zhuo - , Jinan University (Author)
  • Jin Zhang - , Hohai University, CAS - Xinjiang Institute of Ecology and Geography (Author)
  • Mei Li - , Jinan University (Author)
  • Xue Li - , Jinan University (Author)

Abstract

Polycyclic aromatic hydrocarbons (PAHs) are a type of typical environmental pollutant with carcinogenic effects and high ecological risk. With the development of industry, surface water acts as a primary sink for PAHs. Owing to their low solubility, a significant amount of PAHs are adsorbed onto suspended particulate matter in surface water, which presents a serious risk to human health and the ecological environment. To protect human health and aquatic organisms, a systematic assessment of the trends in PAHs exposure risk is essential. Based on long-term monitoring data from 2002 to 2016, this study systematically evaluated the spatiotemporal distribution and source apportionment of PAHs adsorbed on suspended particulate matter in surface water. The results of the Mann-Kendall test indicated that pollution levels of PAHs decreased from 2012 to 2016. The maximum average content was 6 239 μg•kg-1, and the minimum was 2 760 μg•kg-1. Benzo(b)fluoranthene, benzo(k)fluoranthene, chrysene, and benzo(a)anthracene showed significant declines from 2002-2016 (P<0.05). Levels of benzo(a)pyrene, dibenzo(a, h)anthracene, and indeno(1, 2, 3-cd)pyrene were steady. Wavelet analysis showed that the pollution level of PAHs had significant periodic oscillations for surface water. Midstream and downstream ∑16PAHs showed significant declines from 2002-2016 (P<0.05), whereas upstream ∑16PAHs were steady. ANOVA analysis showed that the spatial difference was significant and occurred in the following order: midstream (6 168 μg•kg-1)>upstream (5 407 μg•kg-1)>downstream (3 412 μg•kg-1). Diagnostic ratio analysis and the positive matrix factorization model suggested that the major sources of PAHs were traffic sources, coal burning sources, and biomass combustion sources, which accounted for 40.9%, 33.7%, and 25.4%, respectively. The contribution of traffic sources decreased by 25.9%. The contributions of coal burning sources and biomass combustion sources increased by 4.8% and 21.1% from 2002-2009 to 2010-2016, respectively. These results provide scientific reference for risk analysis and the control of PAHs pollution in surface water.

Translated title of the contribution
Spatiotemporal Distribution and Source Apportionment of Suspended Polycyclic Aromatic Hydrocarbons in Surface Water

Details

Original languageChinese
Pages (from-to)3645-3655
Number of pages11
JournalEnvironmental Science
Volume43
Issue number7
Publication statusPublished - 15 Jul 2022
Peer-reviewedYes

External IDs

PubMed 35791547
Mendeley a273ef2a-88a5-3a21-ad5e-9ca7a6dfc4a1

Keywords

Sustainable Development Goals

ASJC Scopus subject areas

Keywords

  • Polycyclic aromatic hydrocarbons(PAHs), Source apportionment, Temporal and spatial variation characteristics, Uncertainty analysis, Wavelet analysis