Room-Temperature Stimulated Emission and Lasing in Recrystallized Cesium Lead Bromide Perovskite Thin Films

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Neda Pourdavoud - , University of Wuppertal (Author)
  • Tobias Haeger - , University of Wuppertal (Author)
  • Andre Mayer - , University of Wuppertal (Author)
  • Piotr Jacek Cegielski - , AMO GmbH, RWTH Aachen University (Author)
  • Anna Lena Giesecke - , AMO GmbH (Author)
  • Ralf Heiderhoff - , University of Wuppertal (Author)
  • Selina Olthof - , University of Cologne (Author)
  • Stefan Zaefferer - , Max Planck Institute for Iron Research (Author)
  • Ivan Shutsko - , University of Wuppertal (Author)
  • Andreas Henkel - , University of Wuppertal (Author)
  • David Becker-Koch - , Heidelberg University  (Author)
  • Markus Stein - , University of Marburg (Author)
  • Marko Cehovski - , Technical University of Braunschweig, Leibniz University Hannover (LUH) (Author)
  • Ouacef Charfi - , Technical University of Braunschweig, Leibniz University Hannover (LUH) (Author)
  • Hans Hermann Johannes - , Technical University of Braunschweig, Leibniz University Hannover (LUH) (Author)
  • Detlef Rogalla - , Ruhr University Bochum (Author)
  • Max Christian Lemme - , AMO GmbH, RWTH Aachen University (Author)
  • Martin Koch - , University of Marburg (Author)
  • Yana Vaynzof - , Heidelberg University  (Author)
  • Klaus Meerholz - , University of Cologne (Author)
  • Wolfgang Kowalsky - , Technical University of Braunschweig, Leibniz University Hannover (LUH) (Author)
  • Hella Christin Scheer - , University of Wuppertal (Author)
  • Patrick Görrn - , University of Wuppertal (Author)
  • Thomas Riedl - , University of Wuppertal (Author)

Abstract

Cesium lead halide perovskites are of interest for light-emitting diodes and lasers. So far, thin-films of CsPbX3 have typically afforded very low photoluminescence quantum yields (PL-QY ' 20%) and amplified spontaneous emission (ASE) only at cryogenic temperatures, as defect related nonradiative recombination dominated at room temperature (RT). There is a current belief that, for efficient light emission from lead halide perovskites at RT, the charge carriers/excitons need to be confined on the nanometer scale, like in CsPbX3 nanoparticles (NPs). Here, thin films of cesium lead bromide, which show a high PL-QY of 68% and low-threshold ASE at RT, are presented. As-deposited layers are recrystallized by thermal imprint, which results in continuous films (100% coverage of the substrate), composed of large crystals with micrometer lateral extension. Using these layers, the first cesium lead bromide thin-film distributed feedback and vertical cavity surface emitting lasers with ultralow threshold at RT that do not rely on the use of NPs are demonstrated. It is foreseen that these results will have a broader impact beyond perovskite lasers and will advise a revision of the paradigm that efficient light emission from CsPbX3 perovskites can only be achieved with NPs.

Details

Original languageEnglish
Article number1903717
JournalAdvanced materials
Volume31
Issue number39
Publication statusPublished - 1 Sept 2019
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 31402527

Keywords

Keywords

  • cesium lead halide perovskite, distributed feedback lasers, perovskite vertical cavity surface emitting lasers, recrystallization, thermal imprint, thin films