Robust Single Molecule Magnet Monolayers on Graphene and Graphite with Magnetic Hysteresis up to 28 K

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Lukas Spree - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Fupin Liu - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Volker Neu - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Marco Rosenkranz - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Georgios Velkos - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Yaofeng Wang - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Sandra Schiemenz - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Jan Dreiser - , Paul Scherrer Institute (Author)
  • Pierluigi Gargiani - , Autonomous University of Barcelona (Author)
  • Manuel Valvidares - , Autonomous University of Barcelona (Author)
  • Chia Hsiang Chen - , Kaohsiung Medical University (Author)
  • Bernd Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Stanislav M. Avdoshenko - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Alexey A. Popov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

The chemical functionalization of fullerene single molecule magnet Tb2@C80(CH2Ph) enables the facile preparation of robust monolayers on graphene and highly oriented pyrolytic graphite from solution without impairing their magnetic properties. Monolayers of endohedral fullerene functionalized with pyrene exhibit magnetic bistability up to a temperature of 28 K. The use of pyrene terminated linker molecules opens the way to devise integration of spin carrying units encapsulated by fullerene cages on graphitic substrates, be it single-molecule magnets or qubit candidates.

Details

Original languageEnglish
Article number2105516
JournalAdvanced functional materials
Volume31
Issue number48
Publication statusPublished - 25 Nov 2021
Peer-reviewedYes

Keywords

Keywords

  • lanthanide, magnetic hysteresis, metallofullerenes, self-assembled monolayers, single-molecule magnets